Synthesis of sub-micron sized hollow, and nanoporous phenylsiloxane spheres through use of phenyltrimethoxysilane as surfmer: Insights into the surfactant and factors influencing the particle architecture

2019/6/17

A palladium chloride catalyzed Hiyama cross-coupling reaction between aryl halides and Phenyltrimethoxysilane in toluene has been developed. High yields of products, as well as the obviation of ligand are important features of this method. The scope of the reaction is broad, and a wide variety of functional groups are tolerant.