Tetraethoxysilane(Si-28)

  • CAS No.

    78-10-4

  • Molecular Formula :

    C4H20O4Si

  • Purity :

    99%

  • Technical Index :

    Density(ρ20, g/cm3): 0.9340 ± 0.0050
    Refractive Index(n25D): 1.3928 ± 0.0050

  • Packing :

    210LIron Drum:190kg/drum
    1000L IBCContainer: 900kg/container

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Description :
Tetraethoxysilane ( also called orthosilicic acid esters) most commonly used as starting materials for sol-gel. Polysilicic acidesters are condensation products obtained by incomplete hydrolysis or orthosilicic acid esters. They are also be used as starting materials for the sol-gel process. Tetraethoxysilane typical application: Be hydrolyzed to form silicon dioxide (silica). Crosslinkers in silicone rubber systems
Drying agents in sealing compositions
Inorganic binder for refractory fillers and pigments
Coating material for pigments, fibers and other surfaces

Chemical intermediate


Operation  Instruction  of  IBC

Inner layer: 4-fluoroethylene drum, 250 kg volume 220kg net weight, and other Argon Protective Layers

Middle layer: 6-7 layers of foam for earthquake Prevention

Outer layer : Fixation of steel frame or hard plastic shell and bottom silica gel protection

Tetraethoxysilane, formally named Tetraethyl orthosilicate and abbreviated TEOS, is the chemical compound with the formula Si(OC2H5)4. TEOS is a colorless liquid that degrades in water. TEOS is the ethyl ester of orthosilicic acid, Si(OH)4. It is the most prevalent alkoxide of silicon.
TEOS is a tetrahedral molecule. Like its many analogues, it is prepared by alcoholysis of silicon tetrachloride:
SiCl4 + 4 EtOH → Si(OEt)4 + 4 HCl
where Et is the ethyl group, C2H5, and thus EtOH is ethanol.
Tetraethoxysilane Applications
TEOS is mainly used as a crosslinking agent in silicone polymers and as a precursor to silicon dioxide in the semiconductor industry. TEOS is also used as the silica source for synthesis of some zeolites. Other applications include coatings for carpets and other objects. TEOS is used in the production of aerogel. These applications exploit the reactivity of the Si-OR bonds. TEOS has historically been used as an additive to alcohol based rocket fuels to decrease the heat flux to the chamber wall of regeneratively cooled engines by over 50%.
Tetraethoxysilane Other reactions
TEOS easily converts to silicon dioxide upon the addition of water:
Si(OC2H5)4 + 2 H2O → SiO2 + 4 C2H5OH
An idealized equation is shown, in reality the silica produced is hydrated. This hydrolysis reaction is an example of a sol-gel process. The side product is ethanol. The reaction proceeds via a series of condensation reactions that convert the TEOS molecule into a mineral-like solid via the formation of Si-O-Si linkages. Rates of this conversion are sensitive to the presence of acids and bases, both of which serve as catalysts. The St?ber process allows the formation of monodisperse and mesoporous silica.
At elevated temperatures (>600 °C), TEOS converts to silicon dioxide:
Si(OC2H5)4 → SiO2 + 2 (C2H5)2O
The volatile coproduct is diethyl ether.
Tetraethoxysilane Safety
TEOS has low toxicity by ingestion. While tetramethoxysilane is highly damaging to eyes since it deposits silica, TEOS is much less so due to lower hydrolysis rate of the ethoxy groups.

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In situ polymerization of tetraethoxysilane in poly(methyl methacrylate): morphology and dynamic mechanical properties 2019/06/17

Dynamic mechanical spectroscopy and transmission electron microscopy were utilized to investigate the properties of composites resulting from the formation of a cross-linked inorganic network via the polymerization of tetraethoxysilane (TEOS) in situ in a poly(methyl methacrylate) (PMMA) binder. The...

Ignition delay times of shock-heated tetraethoxysilane, hexamethyldisiloxane, and titanium tetraisopropoxide 2019/06/17

Ignition delay times of tetraethoxysilane (TEOS), hexamethyldisiloxane (HMDSO) and titanium tetraisopropoxide (TTIP) were determined from the onset of chemiluminescence in shock-tube experiments behind reflected shock waves in dry as well as in humid gas mixtures. Additionally, the ignition delay ti...

Hydrolysis of tetraethoxysilane by copper(II) salt hydrates 2019/06/16

Hydrolysis of tetraethoxysilane by water catalyzed by small amounts of hydrated copper(II) chloride, copper(II) nitrate and copper(II) perchlorate in ethanol was investigated using 29Si NMR. The results showed significantly faster hydrolysis in the system catalyzed by the perchlorate. One reason for...

Modelling the flame synthesis of silica nanoparticles from tetraethoxysilane 2019/06/15

This work proposes a kinetic model and an inception pathway for the flame synthesis of silica nanoparticles from tetraethoxysilane (TEOS). The kinetic model for the decomposition of TEOS is developed by generating reactions involving species that were reported in high concentrations at equilibrium. ...

Hydrolysis–condensation reactions of diethylphosphato-ethyltriethoxysilane with tetraethoxysilane studied by 29Si-NMR: Solvent and phosphonate catalytic effect 2019/06/13

Hydrolysis and condensation reactions of diethylphosphato-ethyltriethoxysilane (SiP) and a mixture of SiP and tetraethoxysilane (TEOS) have been studied in ethanol and N-methylacetamide (NMA) as solvent. Conditions of reaction used for both SiP and SiP/TEOS mixture were Si/solvent (ethanol or NMA)/w...

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